In recent years, shape memory polymers (SMPs) and self-healing polymers (SHPs) have been research hotspots in the field of smart polymers owing to their unique stimulus response mechanisms. Previous research on SHPs has primarily focused on contact repair. However, in instances where substantial cracks occur during practical use, autonomous closure becomes challenging, impeding effective repair. By integration of the shape memory effect (SME) with SHPs, physical wound closure can be achieved via the SME, facilitating subsequent chemical/physical repair processes and enhancing self-healing effectiveness. This article reviews key findings from previous research on shape memory-assisted self-healing (SMASH) materials and addresses the challenges and opportunities for future investigation.

LANGMUIR   2024,40,15957-15968

Wanting Ting; Ping, Zhongxin; Gong, Xiaobo; Xie, Fang; Liu, Yanju; Leng, Jinsong

https://doi.org/10.1021/acs.langmuir.4c01369

Self-Healing Polymers Coupling Shape Memory Effect_.pdf