Composite Structures 7(2025)055504
Keywords: shape memory polymer nanocomposites 4D printing multiple shape memory effects bio-inspired metamaterials multi-functionality
Metamaterials, owing to their exceptional physical characteristics that are absent in natural materials, have emerged as a crucial constituent of intelligent devices and systems. However, there are still significant challenges that necessitate immediate attention, as they have considerably constrained the applicability of metamaterials, including fixed mechanical properties post-fabrication and restricted design freedom. Here, thermo-responsive, photo-responsive, electro-responsive, and magneto-responsive shape memory polymer nano-composites were developed, and shape memory gradient metamaterials were fabricated using multi-material 4D printing technology. The correlation mechanism between the design parameters and the mechanical properties of multi-responsive gradient metamaterials was systematically analyzed, and the highly designable and programmable configuration and mechanical properties of the gradient metamaterials were realized. More importantly, 4D printed multi-responsive shape memory polymer gradient metamaterials can be programmed in situ without additional infrastructure for multi-functional mechanical functions, paving the way for the realization of multiple functions of a single structure. Based on the multi-responsive gradient metamaterials, 4D printed digital pixel metamaterial intelligent information carriers were fabricated, featuring customizable encryption and decryption protocols, exceptional scalability, and reusability. Additionally, 4D printed gradient metamaterial logic gate electronic devices were developed, which were anticipated to contribute to the development of smart, adaptable robotic systems that combine sensing, actuation, and decision-making capabilities.
The developed 4D-printed multi-responsive gradient metamaterials exhibited high programmability, designability, and multi-functionality. Digital pixel metamaterial intelligent information carriers with customizable encryption/decryption programs, scalability, and reusability were designed.Multi-responsive gradient metamaterial logic gate electronic devices demonstrated application potential in intelligent flexible robotic system.
Chunli Yang , Xiaozhou Xin , Wenjun Zhao , Cheng Lin , Liwu Liu , Yanju Liu , Jinsong leng
Highly programmable 4D printed multi-shape gradient metamaterials and multifunctional devices.pdf